久保田 浩司

久保田浩司 苦労の末、手にした論文です。 kubota_taguchi

受賞歴など

・Springer theses award 2016
・Reaxys PhD Prize 2016 Finalist
 
・Chem Station スポットライトリサーチ

・Pacifichem 2015 ポスター賞 受賞
・第六回大津会議参加・研究企画賞 受賞
・第7回 HOPE Meeting Fellow、優秀プレゼン賞受賞

・日本学術振興会特別研究員(DC1)
カナダUniversity of Alberta 短期留学(Dennis Hall 研究室、2014年1月~3月)
・平成25年度 大塚博先生記念賞
第59回有機金属化学討論会ポスター賞 受賞
北海道大学工学部平成23年度 William Wheeler Prize 受賞

List of publication

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[16] Copper(I)-Catalyzed Regio- and Stereoselective Intramolecular Alkylboration of Propargyl Ethers and Amines
Iwamoto, H.; Ozawa, Y.; Kubota, K.; Ito, H. J. Org. Chem. 2017, accepted
DOI: 10.1021/acs.joc.7b02071

[15] Stereodivergent Hydrodefluorination of gem-Difluoroalkenes: Selective Synthesis of (Z)- and (E)-Monofluoroalkenes
Kojima, R.; Kubota, K.; Ito, H. Chem. Commun. 2017, accepted
DOI: 10.1039/C7CC05225A

[14] Copper(I)-Catalyzed Enantioselective Nucleophilic Borylation of Ketones: Synthesis of Enantioenriched Chiral Tertiary alpha-Hydroxyboronates
Kubota, K.; Osaki, S.; Jin, M.; Ito, H. Angew. Chem. Int. Ed. 2017, 56, 6646 - 6650.
DOI: 10.1002/anie.201702826

北海道大学 PRESS RELEASE 

・Highlighted in Synfacts 201713, 745. DOI: 10.1055/s-0036-1590558

[13] Synthesis of Enantiomerically Enriched Chiral Tetrahydroquinolines via Sequential Dearomatization/Enantioselective Borylation Reactions
Kubota, K.; Watanabe, Y.; Ito, H. Adv. Synth. Catal. 2016, 358, 15, 2379 - 2384.
DOI: 10.1002/adsc.201600372


abstract_quinoline

[12] Computational Insight into the Enantioselective Nucleophilic Borylation of a Polarized C=O Double Bond Catalyzed by Di-phosphine-Borylcopper(I) Complexes
Kubota, K.; Jin, M.; Ito, H. Organometallics 2016, 35, 1376 - 1383.
DOI: 10.1021/acs.organomet.5b00621

 

org

[11] Enantioselective Synthesis of Chiral Piperidines via the Stepwise Dearomatization/Borylation of Pyridines
Kubota, K.; Watanabe, Y.; Hayama, K.; Ito, H. J. Am. Chem. Soc. 2016, 138, 13, 4338 - 4341.
DOI: 10.1021/jacs.6b01375

s1-ln204455595844769-1939656818Hwf1112863307IdV-3045673942044555PDF_HI0001-6

[10] Highly Selective Markovnikov Hydroboration of Alkyl-Substituted Terminal Alkenes with a Phosphine-Copper(I) Catalyst
Iwamoto, H.; Kubota, K.; Ito, H. Chem. Commun. 2016, 5916 - 5919.
DOI: 10.1039/C6CC00782A

MHB_GA_1 (1)   iwamoto_cover
Highlighted as a Back Cover in Issue 35, 2016

[9] Copper(I)-Catalyzed Diastereoselective Borylative Exo-Cyclization of Alkenyl Aryl Ketones
Yamamoto, E.; Kojima, R.; Kubota, K.; Ito, H. Synlett 2015, 26, 2, 272 - 276.
DOI: 10.1055/s-0035-1560721

https://www.thieme-connect.de/media/synlett/EFirst/i_u0477_ga_10-1055_s-0035-1560721.gif

[8] Enantioselective Borylative Dearomatization of Indoles through Copper(I) Catalysis
Kubota, K.; Hayama, K.; Iwamoto, H.; Ito, H. Angew. Chem. Int. Ed. 2015, 54, 8809 - 8813.
DOI: 10.1002/anie.201502964

1511291_784871204944392_5626421871371438753_n

・Highlighted in Synfacts 2015, 11, 840. DOI: 10.1055/s-0034-1381153

[7] Copper(I)-Catalyzed Carbon–Halogen Bond-Selective Boryl Substitution of Alkyl Halides Bearing Terminal Alkene Moieties
Iwamoto, H.; Kubota, K.; Yamamoto, E; Ito, H. Chem. Comm. 2015, 51, 9655 - 9658.
DOI: 10.1039/C5CC02760H

名称未設定名称未設定

[6] Reaction Optimization, Scalability, and Mechanistic Insight on the Catalytic Enantioselective Desymmetrization of 1,1-Diborylalkanes via Suzuki–Miyaura Cross-Coupling
Sun, H.; Kubota, K.; Hall, D. G. Chem. Eur. J. 2015, Early View
DOI: doi/10.1002/chem.201406680

mcontent

[5] Silicon-Tethered Strategy for Copper(I)-Catalyzed Stereo- and Regioselective Alkylboration of Alkynes
Kubota, K.; Iwamoto, H.; Yamamoto, E; Ito, H. Org. Lett. 2015, 17, 620 - 623.
DOI: 10.1021/ol503620n

ol-2014-03620n_0007 

・Highlighted in Synfacts 2015, 11, 406. DOI: 10.1055/s-0034-1380388

 

[4] Copper(I)-Catalyzed Enantioselective Nucleophilic Borylation of Aldehydes: An Efficient Route to Enantiomerically Enriched α-Alkoxyorganoboronate Esters
Kubota, K.; Yamamoto, E.; Ito, H. J. Am. Chem. Soc. 2015, 137, 1, 420 - 424.
DOI: 10.1021/ja511247z

kubotaabs 

・Highlighted in Synfacts 2015, 11, 286. DOI: 10.1055/s-0034-1380053

[3] Regio- and Enantioselective Monoborylation of Alkenylsilanes Catalyzed by an Electron-Donating Chiral Phosphine-opper(I) Complex
Kubota, K.; Yamamoto, E.; Ito, H. Advanced Synthesis & Catalysis 2013, 355, 3527 - 3531.
DOI: 10.1002/adsc.201300765

mcontent

・Highlighted in Synfacts, 2013, 10, 284. DOI: 10.1055/s-0033-1340694

[2] Copper(I)-Catalyzed Borylative Exo-Cyclization of Alkenyl Halides Containing Unactivated Double Bond
Kubota, K.; Yamamoto, E.; Ito, H. J. Am. Chem. Soc. 2013, 135, 2635 - 2640.
DOI: 10.1021/ja3104582

HP1_450

[1] Copper(I)-Catalyzed Boryl Substitution of Unactivated Alkyl Halides
Ito, H.; Kubota, K. Org. Lett. 2012, 14, 890 - 893.
DOI: 10.1021/ol203413w

Abstract Image

Reviews

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[3] Formal Nucleophilic Borylation and Borylative Cyclization of Organic Halides
Kubota, K.; Iwamoto, H.; Ito, H. Org. Biomol. Chem. 2017, 15, 285 - 300.
DOI: 10.1039/C6OB02369J

OBC review

[2] Topochemical Photocyclizations for the Synthesis of Two-Dimensional Polymers
Kubota, K. J. Synth. Org. Chem. Jpn. 2014, 72, 834.
DOI: 10.5059/yukigoseikyokaishi.72.834

[1] Selective Synthesis of Organoboron Compounds with Copper(I)-Phosphine Complex Catalysts
Yamamoto, E.; Takenouchi, Y.; Kubota, K.; Ito, H. J. Synth. Org. Chem. Jpn. 2014, 72, 758 - 769.
DOI: 10.5059/yukigoseikyokaishi.72.758